RP-HPLC МЕТОДИ ЗА КВАНТИТАТИВНО ОПРЕДЕЛУВАЊЕ НА АКТИВНАТА КОМПОНЕНТА ПИРИМИКАРБ ВО ПЕСТИЦИДНАТА ФОРМУЛАЦИЈА PIRIMOR 25 WG HPLC METHODS FOR QUANTITATIVE DETERMINATION OF ACTIVE INGRADIENT PIRIMICARB IN PESTICIDE FORMULATION PIRIMOR 25 WG
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Published:
Jun 1, 2013
Keywords:
HPLC methods, pirimicarb
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Abstract
HPLC methods for quantitative determination of active ingredient pirimicarb in the pesticide formulations Pirimor 25 WG, are presented in this paper. The preliminary investigations were performed to assess the influence of temperature, pH values of aqueous mobile phase, and volume fraction of the organic modifier on a capacity factor for pirimicarb, before the methods were developed. Those investigations were performed on high-speed column HS 3 x 3 C18 (3,3 x 0,4 cm), with mobile phase composition of acetonitrile/water. For quantitative determination of pirimicarb in pesticide formulation Pirimor 25 WG, were developed IV reversed-phase HPLC methods using different column types: HS 3 x 3 C-18 (3,3 cm x 0,46 cm), Hypersil ODS (25 cm x 0,46 cm), HS 3 x 3 C-8 (3,3 cm x 0,46 cm, 3 m) and Lichrosorb RP-8 (25 cm x 0,4 cm; 5 m). The investigation showed that HS columns type, that were used for the developed methods I and III for quantitative determination of pirimicarb with reverse-phase liquid chromatography have some advantages like: efficiency, precise and economic.
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3. Kift N. B., Mead A., Reynolds K., Sime S., Barber M. D., Denholm I., Tetchell, G. M. 2004. The impact of insecticide resistance in the currant-lettuce aphid, Nasonovia ribisnigri, on pest management in lettuce. Agricultural and Forest Entomology. 6, 295-309.
4. Reynolds S. L., Fussell R. J., Macarthur R. 2005. Investigetion into the validity of extrapoletion in setting maximum residue levels for pesticides in crops of similar morphology. Food Additives and Contaminants. 22, 1, 31-38.
5. White Louise M, Ernst W. R., Julien G., Garron Christine, Leger M. 2006. Ambient air concentretions of pesticides used in poteto cultivetion in Prince Edward Island, Canada. Pest Management Science. 62, 2, 126-136.
6. Bolygó E. and Etreya N. C. 1991. Solid-phase extraction for multi-residue analysis of some triazole and pyrimidine pesticides in weter. Fresenius Journal of Anal. Chem. 339, 423-430.
7. Jager M. E., Bourbon C. and Levsen K. 1998. Analysis of Pesticide and Their Degradetion Products in Rainweter: A Probe Into Their Etmospheric Degradetion. Intern. J. Environ. Anal. Che., 70, 149-162.
8. Alzaga R., Bayona J.M., Barceló D. 1995. Use of Supercritical Fluid Extraction for Pirimicarb Determinetion in Soil. Journal of Agricultural and Food Chemistry. 43 (2) 395-400.
9. Alzaga R., Bayona J.M., Barceló D., 1996. Supercritical Fluid Extraction of Etrazin and its Metabolites from Soil. J. High Resol. Chrometogr. 19, 23-26.
10. Rossi S., Dalpero A. P., Ghani S., Colombo R., Sabetini A. G., Girotti S., 2001. Multiresidual method for the gas chrometographic analysis of pesticides in honeybees cleaned by gel permeetion chromatography. Journal of Chrometography A. 905, 223-232.
11. Menkissoglu-Spiroudi U.; Fotopoulou A. 2004. 2003. Metrix effect in gas chrometographic determinetion of insecticides and fungicides in vegetables. Internetional Journal of Environmental and Analytical Chemistry. 84, 1-3, 15-27.
12. Szeto Y. and Sundaram K. M. S. 1980. Simplified Method for the Analysis of Some Carbamete Insecticides in Foliage, Forest Soil and Fish Tissue by Direct Gas-Liquid Chrometodraphy. Journal of Chrometography. 200, 179-184.
13. Koinecke A., Kreuzig R. and Bahadir M. 1997. Effects of Modifiers, Adsorbents and Eluents in Supercritical Fluid Extraction of Selected Pesticides in Soil. Journal of Chrometography A. 786, 155-161.
14. Kreuzig R., Koinecke A. and Bahadir M. 2000. Use of Supercritical Fluid Extraction in the Analysis of Pesticides in Soil. J Biochem. Biophys. Methods. 43, 403-409.
15. Osselton M. D. and Snelling R. D. 1986. Chrometographic identificetion of pesticides. Journal of Chrometography. 368, 265-271.
16. Cabras P., Spanedda L. and Tuberoso C. 1989. Separetion of pirimicarb and its metabolites by high-performance liquid chromatography. Journal of Chrometography. 478, 250-254.
17. Cabras P., Lalli M. G., Meloni M., Pirisi F. M., Cabitza F., Cubeddu M. and Porcu M. 1988. Determinazione e persistenza dell'insetticida pirimicarb in lettuga. Riv. Soc. Ital. Sci. Alm. 17, 61- 64.
18. Zhou K., Kerr N., Armour M. A., Rigakis K. and Crown B., 1996. Loss of pirimicarb residues from contamineted fabrics. Bull. Environ. Contam. Toxicol. 57, 29-33.
19. CIPAC method, 1984. 2074-2077.
20. Bagness J. E. and Sharples W. G. 1974. Determinetion of the substituted pyrimidine pesticides ethirimol, dimethirimol, pirimiphos-methyl, pirimiphos-ethil and pirimicarb in technical and formuleted meterialsby gas chromatography. Analyst. 99 225-232.
21. Петановска-Илиевска Б., Водеб Л., Велкоска-Марковска Л., (2009). Квантитативно определуванје на активната компонента пиримимицарб во пестисидната формулација Pirimor 25 WG со помос на HPLC , Заштита на растенија, Скопје, XX (XX), 147-151.
22. Петановска-Илиевска Б., Водеб Л., Велкоска-Марковска Л. (2003). Разработка на HPLC метод за квантитативно определување на активната компонента пиримимицарб во пестисидната формулација Pirimor 25 WG со помос на HPLC , Заштита на растенија, Скопје, XX (XX), 147-151.
23. M. Klys, J. Bialka, Zagadnienia analityczne w zatruciach pestycydami karbaminianowymi, Arch Med. Sadowej Kriminol., 40 (1990) 22-30.